New general synthesis of α-alkoxyketones via α′-alkylation, α-alkylation and α,α′-dialkylation of α-alkoxyketimines
نویسندگان
چکیده
منابع مشابه
New general synthesis of a-alkoxyketones via a¢-alkylation, a-alkylation and a,a¢-dialkylation of a-alkoxyketimines†
a-Methoxyand a-ethoxyketones, as important intermediates in organic synthesis and flavor compounds in food chemistry, were synthesized by deprotonation of N-(1-alkoxy-2-propylidene)isopropylamine, prepared by condensation of the corresponding a-alkoxyacetone with isopropylamine, and subsequent reaction of the corresponding 1-azaallylic anions with alkyl halides to afford a¢-alkylated, a-alkylat...
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ژورنال
عنوان ژورنال: Org. Biomol. Chem.
سال: 2011
ISSN: 1477-0520,1477-0539
DOI: 10.1039/c0ob00662a